Rubber is the main raw material in the production of rubber products. Although the amount of compounding agent is small, it is an indispensable raw material. The compounding agent not only determines the physical and mechanical properties of the vulcanizate and the performance and service life of the product, but also affects the processing technology of the rubber compound. Vulcanization accelerator can accelerate the reaction between vulcanizing agent and rubber to shorten the vulcanization time. Thiazole accelerators are commonly used accelerators in rubber, so what are the characteristics of thiazole accelerators and how to use them?
1. Characteristics of thiazole accelerators
Thiazole accelerators are acidic quasi-speed accelerators with higher activity than sulfenamides, but lower than thiurams and dithiocarbamates. Accelerator M is one of the most widely used in rubber products, as well as accelerators DM/MZ/CZ/DZ, etc.
Thiazole accelerators have high vulcanization activity, fast vulcanization rate, good vulcanization flatness, medium scorch time, and good safety in actual operation; vulcanizate has good comprehensive physical and mechanical properties, with high High tensile strength and elongation at break; moderate tensile stress and hardness, good wear resistance and aging resistance, small compression set, etc. It is widely used in rubber.
2. Application of thiazole accelerators
The combined use of thiazole accelerators and weak accelerators of guanidine or aldehyde amines can improve the activity of the accelerators, shorten the vulcanization time and reduce the vulcanization temperature, and at the same time improve the tensile strength, tensile strength and wear resistance of the vulcanizate. Commonly used types are accelerator M and accelerator D, and accelerator M and accelerator DM/TMTD are used together.
The combined use of thiazole accelerators and sulfenamide HY14S10J2L accelerators, although detrimental to the delayed effect of the vulcanization system, can increase the vulcanization speed by using a small amount of thiazole accelerators when higher retardation is not required.
3. Application of thiazoles in rubber products
Thiazole accelerators are suitable for white, light-colored and transparent rubber products. Among them, the accelerator M is used as the accelerator, and can also be used as the precursor of sulfenamide accelerators.
Thiazole accelerators can be used in the production of reclaimed rubber inner tubes, hoses, tires, tapes, reclaimed rubber shoes and other rubber products. In the actual production process, according to the actual situation, the matching system is reasonably selected, and the dosage of thiazole accelerators is reasonably arranged, so that the vulcanization speed can be optimized, the vulcanization flatness is good, and the performance of the vulcanizate can be improved at the same time.
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